Conversion of cyclic trithiocarbonates to thioacetals, including 1, 3-dithiane, by reduction with diisobutylaluminium hydride (DIBAL)

U Jordis, M Rudolf

文献索引：Jordis, Ulrich; Rudolf, Manfred Phosphorus and Sulfur and the Related Elements, 1984 , vol. 19, p. 279 - 284

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被引用次数: 10

摘要

Abstract Cyclic trithiocarbonates can be desulfurized with diisobutylaluminium hydride (DIBAL) to form the corresponding thioacetals. This new synthetic pathway was exploited for the preparation of several Umpolung reagents, including 1, 3-dithiane. An efficient isolation of sodium trithiocarbonate is described.