Journal of organometallic chemistry

The catalytic synthesis of thiacrowns from thiiranes by Group VI and VII transition metal carbonyl complexes

RD Adams, KM Brosius, OS Kwon

文献索引：Adams, Richard D.; Brosius, Kellie M.; Kwon, O.-Sung Journal of Organometallic Chemistry, 2002 , vol. 652, # 1-2 p. 51 - 59

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被引用次数: 7

摘要

The synthesis of thiacrowns by the catalytic ring opening cyclooligomerization of thiirane has been investigated by using some Group VI and Group VII metal carbonyl complexes. The Group VI catalyst precursors were transition metal complexes of the form M (NCCH3)(PR3) x (CO) 5− x (x= 0, M= Cr, Mo and W; x= 1, M= Cr, R= Ph; M= W, R= Ph, or OC6H4–p-Me). For Group VII, the manganese carbonyl cations:[Mn (NCCH3)(L)(CO) 4]+, L= CO, PPh3, ...