Intramolecular homolytic displacements. 30. Functional decarbonylative transformations of aldehydes via homolytically induced decomposition of unsaturated …

M Degueil-Castaing, L Moutet…

文献索引：Degueil-Castaing, Marie; Moutet, Laurent; Maillard, Bernard Journal of Organic Chemistry, 2000 , vol. 65, # 13 p. 3961 - 3965

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被引用次数: 5

摘要

Homolytically induced decompositions of unsaturated peroxyacetals, synthesized from aldehydes, gave alkoxyalkoxyl radicals that yielded alkyl radicals by rapid β-scission. The latter radicals could react with several types of “transfer agents” to smoothly bring about homolytic decarbonylative functional group transformations of aldehydes into halides, hydrocarbons, xanthates, alkanenitriles, 2-alkyl-3-chloromaleic anhydrides, 1-phenylalk-1 ...