… of the enantioselective properties of the quinohemoprotein alcohol dehydrogenase of Acetobacter pasteurianus LMG 1635. 1. Different enantiomeric ratios of whole …

SS Machado, U Wandel, JA Jongejan…

文献索引：Machado, Sonia Salgueiro; Wandel, Ute; Jongejan, Jaap A.; Straathof, Adrie J. J.; Duine, Johannis A. Bioscience, Biotechnology and Biochemistry, 1999 , vol. 63, # 1 p. 10 - 20

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被引用次数: 11

摘要

Resting cells of Acetobacter pasteurianus LMG 1635 (ATCC 12874) show appreciable enantioselectivity (E= 16-18) in the oxidative kinetic resolution of racemic 2, 3-epoxy-1- propanol, glycidol. Distinctly lower values (E= 7-9) are observed for the ferricyanide-coupled oxidation of glycidol by the isolated quinohemoprotein alcohol dehydrogenase, QH-ADH, which is responsible for the enantiospecific oxidation step in whole cells. The accuracy of ...