Bulletin of the Chemical Society of Japan

Asymmetric hydrogenation with chiral aminophosphine-rhodium complexes and chiral recognition by bisphosphine-rhodium complexes in the asymmetric …

K Onuma, T Ito, A Nakamura

文献索引：Onuma, Ken-ichi; Ito, Tomiyasu; Nakamura, Asao Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 7 p. 2016 - 2019

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被引用次数: 21

摘要

The asymmetric hydrogenation of α-acylaminocinnamic acids with the rhodium complex of (1R, 2R)-1, 2-bis (N-diphenylphosphino-N-methylamino) cyclohexane has been reported to give preferentially (S)-amino acids. On the contrary, it has been found that the enantiomeric (R)-amino acids are obtained by hydrogenation with the rhodium complex of (1R, 2R)-1, 2- bis (diphenylphosphinamino) cyclohexane. The study of the inversion of the ...