Isolation and characterization of reactive intermediates and active catalysts in homogeneous catalysis

PG Gassman, DW Macomber…

文献索引：Gassman,P.G.; Macomber,D.W. Journal of the American Chemical Society, 1985 , vol. 107, p. 2380

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被引用次数: 40

摘要

Abstract: A new method has been developed for the isolation and characterization of highly reactive intermediates and of active catalysts in homogeneous catalysis by transition-metal complexes. Using the principles of steric exclusion type chromatography, a method has been devised for the isolation of highly reactive intermediates on the surface of porous polymer films. Analysis of these surface-isolated intermediates by X-ray photoelectron ...