Synlett

One Pot Deprotective Oxidation of O-Allyl Ethers Using 70% tert-Butyl Hydroperoxide and Catalytic CrO3

S Chandrasekhar, PK Mohanty, T Ramachander

文献索引：Chandrasekhar; Mohanty, Pradyumna K.; Ramachander Synlett, 1999 , # 7 p. 1063 - 1064

全文：HTML全文

被引用次数: 4

摘要

Abstract: Deprotection of O-allyl ether and in situ oxidation of the liberated free hydroxy group to carbonyl functionality is achieved in one pot using 70% tert-Butyl Hydroperoxide and catalytic CrO3. Other sensitive groups viz.,-OTHP,-OTBDMS and–OMOM ethers survive under the reaction conditions. Key words: protecting groups, allylation, oxidation, catalyst, one pot reaction