Electrochemical coupling of activated olefins and alkyl dihalides: formation of cyclic compounds

…, JY Nedelec, JC Folest, J Perichon

文献索引：Lu, Yu-Wei; Nedelec, Jean-Yves; Folest, Jean-Claude; Perichon, Jacques Journal of Organic Chemistry, 1990 , vol. 55, # 8 p. 2503 - 2507

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被引用次数: 20

摘要

The electrochemical coupling of dimethyl maleate, methyl cinnamate, 4-phenyl-3-buten-2- one, or methyl acrylate with dibromomethane, 1, 3-dibromopropane, 1, 4-dibromobutane, or other substituted alkyl dihalides gave satisfactory yields of cyclic products. The reactions were performed in an undivided cell fitted with a sacrificial aluminum anode, in N- methylpyrrolidone (NMP), at constant current, and at room temperature. The role of the ...