Reactions of iron (II) nitrilotriacetate and iron (II) ethylenediamine-N, N'-diacetate complexes with hydrogen peroxide

JD Rush, WH Koppenol

文献索引：Rush, J. D.; Koppenol, W. H. Journal of the American Chemical Society, 1988 , vol. 110, # 15 p. 4957 - 4963

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被引用次数: 121

摘要

Abstract: Reactions of ferrous nitrilotriacetate (nta) and ethylenediamine-A', N'-diacetate (edda) complexes with hydrogen peroxide at neutral pH in the presence of formate lead to transient intermediates characterized by absorptions near 280 and 400 nm as previously observed for hedta as a ligand. The decomposition of hydrogen peroxide by Fe"'nta and- edda leads to ligand destruction, which is not inhibited by formate. During this process a ...