The Journal of Organic Chemistry

Electrophilic mercuration reactions of derivatives of deuteroporphyrin IX: new syntheses of coproporphyrin III, harderoporphyrin, isoharderoporphyrin, and S-411 …

KM Smith, KC Langry

文献索引：Smith, Kevin M.; Langry, Kevin C. Journal of Organic Chemistry, 1983 , vol. 48, # 4 p. 500 - 506

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被引用次数: 38

摘要

Treatment of copper (I1) deuteroporphyrin IX dimethyl ester (17) with mercuric acetate affords a peripherally metalated species in which the 2-and 4-positions are mercurated. Acidic deuterolysis and sodium borodeuteride reduction suggest that some mercury also becomes attached to the a and p meso positions. Treatment of the dimercurated material with methyl acrylate and LiPdCla gives the corresponding diacrylate, 8, which can be ...