Journal of Organometallic Chemistry

Chloroboration and allied reactions of unsaturated compounds: V. Haloboration and phenylboration of olefins; and the preparation of hexaphenyl-1, 4- …

F Joy, MF Lappert, B Prokai

文献索引：Joy,F. et al. Journal of Organometallic Chemistry, 1966 , vol. 5, p. 506 - 519

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被引用次数: 27

摘要

Abstract The reactions of boron halides (Cl, Br) and of some organoboron chlorides with olefins have been investigated. Detailed results are presented on cyclohexene, allene, 1, 5- cyclooctadiene, norbornadiene, cyclooctatetraene, and cycloheptatriene. It is clear that boron trichloride reacts only with the most reactive of olefins (the last three), so that the first- formed product may react further and prevent the reversible dechloroboration. Similar ...