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J. Chem. Soc., Perkin Trans. 1

Glycoluril† as an efficient molecular template for intramolecular Claisen-type condensations

S Sun, L Edwards, P Harrison

文献索引:Sun, Sengen; Edwards, Louise; Harrison, Paul Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 3 p. 437 - 448

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被引用次数: 26

摘要

The readily prepared 3, 4, 7, 8-tetramethylglycoluril 1 acts as a template to promote efficient intramolecular Claisen-like condensations between two acyl groups which are attached to the-1 and-6 positions. Thus, two sequential acylations of 1 give symmetric or unsymmetric diacylglycolurils 9–18 in good yield. Treat