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An Investigation of the Possibility of Benzopyrylium Salt Formation by Hydrocarbon Elimination from Chromens1

RC Elderfield, TP King

文献索引:Elderfield; King Journal of the American Chemical Society, 1954 , vol. 76, p. 5439,5443

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被引用次数: 9

摘要

In the preceding paper3 evidence was presented to show that the formation of 2, 4, 6- triphenylpyrylium salts from acetophenone does not proceed by ejection of a methyl group iron an intermediate pyran as had been suggested previously. Although such elimination of a hydrocarbon fragment does not occur in this particular instance] the possibility that, under favorable conditions, elimination of a methyl group from an oxygen heterocycle may occur ...