Chemistry of diazocarbonyl compounds: XXVII. Thermolysis and photolysis of diazirines, derivatives of 1, 3-dioxane-4, 6-dione

VV Shevchenko, NN Khimich, MS Platz…

文献索引：Shevchenko; Khimich; Platz; Nikolaev Russian Journal of Organic Chemistry, 2006 , vol. 42, # 8 p. 1213 - 1219

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被引用次数: 9

摘要

Abstract Photolysis of diazirines, 1, 3-dioxane-4, 6-dione derivatives, occurs in the presence of methanol or dimethyl sulfide as carbene traps without a formation of carbene intermediates. It was established for the first time that the thermolysis and photolysis of diazirines from the 1, 3-dioxane-4, 6-dione series led mainly to Wolff rearrangement with a subsequent formation of 5-oxo-1, 3-dioxolane-4-carboxylic acids or their derivatives. The ...