Direct Synthesis of Imines via Solid State Reactions of Carbamates with Aldehydes

…, KH Lee, BW Lim, J Cho, W Nam…

文献索引：Lee, Byeongno; Lee, Kyu Hyung; Lim, Byung Wook; Cho, Jaeheung; Nam, Wonwoo; Hur, Nam Hwi Advanced Synthesis and Catalysis, 2013 , vol. 355, # 2-3 p. 389 - 394

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被引用次数: 3

摘要

Abstract Various solid carbamates were prepared from the reactions of liquid amines with carbon dioxide in an autoclave and these carbamates were used as stable, efficient alternatives for toxic liquid amines. Solid-state grinding of carbamates and aldehydes, using a mortar and pestle, produced imines as the sole products in greater than 97% yields. Complete conversions were generally accomplished within a day at 25 C without using ...