Efficient oxidative cleavage of oximes to their corresponding carbonyl compounds with chromic acid supported on kieselguhr under heterogeneous conditions

…, LH Huang, C Zhang, Q Wang, XN Zou

文献索引：Lou, Ji-Dong; Lu, Xiu Lian; Huang, Li-Hong; Zhang, Changhe; Wang, Qiang; Zou, Xiao-Nan Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2011 , vol. 41, # 10 p. 1278 - 1281

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被引用次数: 3

摘要

An efficient oxidative cleavage of oximes to their corresponding carbonyl compounds with chromic acid supported on kieselguhr reagent under heterogeneous conditions at reflux with a yield between 86 and 96% is described. In these reaction conditions, deoximation of aldoximes required a longer reaction time than that of ketoximes, and the conditions are not suitable for deoximation of aliphatic aldoximes.