Phosphorus and Sulfur and the Related Elements

LIGAND COUPLING THROUGH HYPERVALENT INTERMEDIATES. REACTION OF HETEROARYL SULFOXIDES WITH ORGANOMETALLICS REAGENTS AND …

S Oae

文献索引：OAE, S. Phosphorus and Sulfur and the Related Elements, 1986 , vol. 27, p. 13 - 30

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被引用次数: 28

摘要

Abstract Earlier, pentacoordinate phosphorus and sulfur compounds were presumed to be of 3sp3d hybridization. 1 However, a three-centered-four-electron bond, called a hypervalent bond by Musher, 2 was suggested by Rundle and others3 to be consistent with p-orbitals in the early 1950s. The structure of one such compound, SF4, is shown below. Although the original theoretical treatment of hypervalent structure using three sp2-and a ...