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Stable Nickel (0) Phosphites as Catalysts for C N Cross??Coupling Reactions

…, AN Sobolev, GA Koutsantonis…

文献索引:Kampmann, Sven S.; Sobolev, Alexandre N.; Koutsantonis, George A.; Stewart, Scott G. Advanced Synthesis and Catalysis, 2014 , vol. 356, # 9 p. 1967 - 1973

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被引用次数: 13

摘要

Abstract: Herein we describe the design and preparation of inexpensive, air-stable nickel phosphitebased catalysts for use in the CÀN cross-coupling reaction. The combination of nickel tetrakis (triphenyl phosphite){Ni [PACHTUNGTRENNUNG (OPh) 3] 4} and 1, 1'-bis (diphenylphosphino) ferrocene (dppf), and in particular a newly developed catalyst (dppf) Ni [PACHTUNGTRENNUNG (OPh) 3] 2, were found to be extremely effective in catalyzing a ...