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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Tetrahedron

Total synthesis of maesanin and analogues

S Poigny, M Guyot, M Samadi

文献索引：Poigny, Stephane; Guyot, Michele; Samadi, Mohammad Tetrahedron, 1998 , vol. 54, # 49 p. 14791 - 14802

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被引用次数: 39

摘要

An efficient total synthesis of maesanin and related quinones is reported, through direct alkylation of 1, 2, 4, 5-tetramethoxybenzene with alkylbromides, followed by oxidation with ceric ammonium nitrate (CAN) which provokes formation of the quinone and deprotection of the more hindered methyl ether in one step, to furnish the desired 2-hydroxy-5-methoxy-1, 4- benzoquinones 1a-h.

1,2,4,5-tetramethoxy-3-tridecylbenzene结构式

1,2,4,5-tetrame...

~54%

2-羟基-5-甲氧-3-十三烷基[1,4]苯醌结构式

2-羟基-5-甲氧-3-十三烷...

2,5-DIMETHOXY-3-TRIDECYL-[1,4]BENZOQUINONE结构式

2,5-DIMETHOXY-3...

1,2,4,5-四甲氧基苯结构式

1,2,4,5-四甲氧基苯

~%

2-羟基-5-甲氧-3-十三烷基[1,4]苯醌结构式

2-羟基-5-甲氧-3-十三烷...

2,4,5-三甲氧基苯甲醛结构式

2,4,5-三甲氧基苯甲醛

~%

2-羟基-5-甲氧-3-十三烷基[1,4]苯醌结构式

2-羟基-5-甲氧-3-十三烷...

2,4,5-三甲氧基苯酚结构式

2,4,5-三甲氧基苯酚

~%

2-羟基-5-甲氧-3-十三烷基[1,4]苯醌结构式

2-羟基-5-甲氧-3-十三烷...

1,2,4,5-tetramethoxy-3-tridecylbenzene结构式

1,2,4,5-tetrame...

~%

2-羟基-5-甲氧-3-十三烷基[1,4]苯醌结构式

2-羟基-5-甲氧-3-十三烷...

(Z)-1-(2,3,5,6-tetramethoxyphenyl)-10-pentadecene结构式

(Z)-1-(2,3,5,6-...

~60%

2,5-Cyclohexadiene-1,4-dione, 2-hydroxy-5-methoxy-3-(10-pentadecenyl)- , (Z)-结构式

2,5-Cyclohexadi...

未登录结构式

1,9-二溴壬烷结构式

1,9-二溴壬烷

~%

2,5-Cyclohexadiene-1,4-dione, 2-hydroxy-5-methoxy-3-(10-pentadecenyl)- , (Z)-结构式

2,5-Cyclohexadi...

15-bromopentadec-5-yne结构式

15-bromopentade...

~%

2,5-Cyclohexadiene-1,4-dione, 2-hydroxy-5-methoxy-3-(10-pentadecenyl)- , (Z)-结构式

2,5-Cyclohexadi...

1-己炔结构式

~%

2,5-Cyclohexadiene-1,4-dione, 2-hydroxy-5-methoxy-3-(10-pentadecenyl)- , (Z)-结构式

2,5-Cyclohexadi...

1,2,4,5-四甲氧基苯结构式

1,2,4,5-四甲氧基苯

~%

2,5-Cyclohexadiene-1,4-dione, 2-hydroxy-5-methoxy-3-(10-pentadecenyl)- , (Z)-结构式

2,5-Cyclohexadi...

2,4,5-三甲氧基苯甲醛结构式

2,4,5-三甲氧基苯甲醛

~%

2,5-Cyclohexadiene-1,4-dione, 2-hydroxy-5-methoxy-3-(10-pentadecenyl)- , (Z)-结构式

2,5-Cyclohexadi...

2,4,5-三甲氧基苯酚结构式

2,4,5-三甲氧基苯酚

~%

2,5-Cyclohexadiene-1,4-dione, 2-hydroxy-5-methoxy-3-(10-pentadecenyl)- , (Z)-结构式

2,5-Cyclohexadi...

15-bromopentadec-5-ene结构式

15-bromopentade...

~%

2,5-Cyclohexadiene-1,4-dione, 2-hydroxy-5-methoxy-3-(10-pentadecenyl)- , (Z)-结构式

2,5-Cyclohexadi...

(Z)-1-(2,3,5,6-tetramethoxyphenyl)-10-pentadecene结构式

(Z)-1-(2,3,5,6-...

~%

2,5-Cyclohexadiene-1,4-dione, 2-hydroxy-5-methoxy-3-(10-pentadecenyl)- , (Z)-结构式

2,5-Cyclohexadi...

1,7-二溴庚烷结构式

1,7-二溴庚烷

~%

2-hydroxy-3-[(E)-9-methoxytridec-10-en-6-yl]cyclohexa-2,5-diene-1,4-dione结构式

2-hydroxy-3-[(E...

未登录结构式

~%

2-hydroxy-3-[(E)-9-methoxytridec-10-en-6-yl]cyclohexa-2,5-diene-1,4-dione结构式

2-hydroxy-3-[(E...

1-己炔结构式

~%

2-hydroxy-3-[(E)-9-methoxytridec-10-en-6-yl]cyclohexa-2,5-diene-1,4-dione结构式

2-hydroxy-3-[(E...

未登录结构式

~51%

2-hydroxy-3-[(E)-9-methoxytridec-10-en-6-yl]cyclohexa-2,5-diene-1,4-dione结构式

2-hydroxy-3-[(E...

未登录结构式

1,2,4,5-四甲氧基苯结构式

1,2,4,5-四甲氧基苯

~%

2-hydroxy-3-[(E)-9-methoxytridec-10-en-6-yl]cyclohexa-2,5-diene-1,4-dione结构式

2-hydroxy-3-[(E...

2,4,5-三甲氧基苯甲醛结构式

2,4,5-三甲氧基苯甲醛

~%

2-hydroxy-3-[(E)-9-methoxytridec-10-en-6-yl]cyclohexa-2,5-diene-1,4-dione结构式

2-hydroxy-3-[(E...

2,4,5-三甲氧基苯酚结构式

2,4,5-三甲氧基苯酚

~%

2-hydroxy-3-[(E)-9-methoxytridec-10-en-6-yl]cyclohexa-2,5-diene-1,4-dione结构式

2-hydroxy-3-[(E...

1-bromo-(Z)-8-tridecene结构式

1-bromo-(Z)-8-t...

~%

2-hydroxy-3-[(E)-9-methoxytridec-10-en-6-yl]cyclohexa-2,5-diene-1,4-dione结构式

2-hydroxy-3-[(E...

未登录结构式

~%

2-hydroxy-3-[(E)-9-methoxytridec-10-en-6-yl]cyclohexa-2,5-diene-1,4-dione结构式

2-hydroxy-3-[(E...

15-bromopentadec-5-yne结构式

15-bromopentade...

~%

15-bromopentadec-5-ene结构式

15-bromopentade...

1,9-二溴壬烷结构式

1,9-二溴壬烷

~%

15-bromopentadec-5-ene结构式

15-bromopentade...

1-己炔结构式

~%

15-bromopentadec-5-ene结构式

15-bromopentade...

First synthesis of N-(3-carboxylpropyl)-5-amino-2-hydroxy-3-...

[McErlean, Christopher S. P.; Moody, Christopher J. Journal of Organic Chemistry, 2007 , vol. 72, # 26 p. 10298 - 10301]

Chemical studies of the Proteaceae. VIII. The conversion of ...

[Croft,J.A. et al. Australian Journal of Chemistry, 1976 , vol. 29, p. 1979 - 1987]

Chemical studies of the Proteaceae. VIII. The conversion of ...

[Croft,J.A. et al. Australian Journal of Chemistry, 1976 , vol. 29, p. 1979 - 1987]

Chemical studies of the Proteaceae. VIII. The conversion of ...

[Croft,J.A. et al. Australian Journal of Chemistry, 1976 , vol. 29, p. 1979 - 1987]