Selective Tandem Synthesis of Oximes from Benzylic Alcohols Catalyzed with 2, 3-Dichloro-5, 6-dicyanobenzoquinone

G Aghapour, S Mohamadian

文献索引：Aghapour, Ghasem; Mohamadian, Samaneh Bulletin of the Korean Chemical Society, 2012 , vol. 33, # 4 p. 1209 - 1212

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被引用次数: 2

摘要

Abstract In spite of many reports in the literature concerning with oxidation of benzylic alcohols to carbonyl compounds with 2, 3-dichloro-5, 6-dicyanobenzoquinone (DDQ) in stoichiometric amounts or even more, we surprisingly found that benzylic alcohols are directly oxidized to oximes using a catalytic amount of DDQ in the presence of hydroxylamine hydrochloride under solvent-free conditions. The present tandem catalytic ...