A Comparison between Kinetic Parameters from the Synthesis of Tris (p-nitrophenyl) phosphite and Tris (p-nitrophenyl) phosphate Using Reaction Calorimetry

RC Seiceira, CFP Machado e Silva…

文献索引：Seiceira, Rafael C.; Machado E Silva, Carlos F. P.; Estevao, Luciana R. M.; Cajaiba Da Silva, Joao F. Organic Process Research and Development, 2003 , vol. 7, # 6 p. 954 - 956

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被引用次数: 1

摘要

Tris (p-nitrophenyl) phosphite was prepared by a modification of a “one-pot” methodology developed for the preparation of triaryl phosphates. This exothermic reaction was performed in a Mettler RC-1 calorimeter. The principal aim of this work was to compare the reactivity of phosphorus trichloride and phosphorus oxychloride in their reactions with sodium p- nitrophenoxide. The reaction rate and the reaction rate constant for the synthesis of tris (p- ...