Journal of fluorine chemistry

Reactivite des esters sulfoniques et pyrosulfoniques perfluores RFSO3RF et RFSO3SO3RF heterolyse de la liaison S O

M Oudrhiri-Hassani, D Brunel, A Germain

文献索引：Oudrhiri-Hassani, M.; Brunel, D.; Germain, A Journal of Fluorine Chemistry, 1986 , vol. 32, p. 163 - 178

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被引用次数: 2

摘要

Abstract Perfluoroalkyl perfluoroalkanesulfonates RF SO 3 R′ F (RF, R′ F CF 3, C 2 F 5) and perfluoroalkyl perfluoroalkanepyrosulfonates RF SO 3 SO 3 RF, mixed with perfluoroalkanesulfonic acids (CF 3 SO 3 H or C 2 F 5 SO 3 H) decompose thermally. Depending on the starting materials, different products result from nucleophilic attack of a perfluoroalkanesulfonate anion of the acid on the sulfur atom of the sulfonate group of the ...