Tetrahedron

Facile and selective cleavage of allyl ethers, amines and esters using polymethylhydrosiloxane–ZnCl 2/Pd (PPh 3) 4

S Chandrasekhar, CR Reddy, RJ Rao

文献索引：Chandrasekhar; Raji Reddy; Jagadeeshwar Rao Tetrahedron, 2001 , vol. 57, # 16 p. 3435 - 3438

被引用次数: 58

摘要

Allyl deprotection to liberate free hydroxy, amino and acid groups from the corresponding allyl ethers, amines and esters is achieved under mild conditions. The reagent combination employed for this transformation is polymethylhydrosiloxane (PMHS), ZnCl2 and Pd (PPh3) 4.

~85%

~92%

~88%

~86%

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