Tetrahedron letters

Catalytic aerobic oxidative decarboxylation of α-hydroxy-acids. Methyl mandelate as a benzoyl anion equivalent

…, I Fernández, P Formentin, JR Pedro, AL Roselló…

文献索引：Blay, Gonzalo; Fernandez, Isabel; Formentin, Pilar; Pedro, Jose R.; Rosello, Antonio L.; Ruiz, Rafael; Journaux, Yves Tetrahedron Letters, 1998 , vol. 39, # 20 p. 3327 - 3330

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被引用次数: 21

摘要

The monomeric square-planar cobalt (III) complex of bis-N, N′-disubstituted oxamides catalyses the oxidative decarboxylation of α-hydroxy acids with molecular oxygen/pivalaldehyde with very good yields. This reaction offers an interesting alternative in the use of methyl mandelate as a convenient benzoyl anion equivalent.