HPLC studies on the photochemical formation of free radicals from malonic acid

…, HD Försterling, Z Noszticzius

文献索引：Szalai, Istvan; Foersterling, Horst-Dieter; Noszticzius, Zoltan Journal of Physical Chemistry A, 1998 , vol. 102, # 18 p. 3118 - 3120

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被引用次数: 16

摘要

In the Belousov Zhabotinsky reaction, malonyl radicals formed during the oxidation of malonic acid by Ce4+ play an important role in the mechanism of the negative feedback loop. In the past, we have analyzed the end products in the Ce4+-malonic acid reaction applying HPLC technique. For comparison, we generated malonyl radicals by UV irradiation of solutions of malonic acid and we identified the reaction products. Two of these are the ...