Bulletin of the Chemical Society of Japan

Non-catalyzed thermal reactions of acylquinones with allylstannanes

K Maruyama, Y Matano

文献索引：Maruyama; Matano Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 12 p. 3877 - 3885

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被引用次数: 16

摘要

Thermal reactions of acylquinones with allylstannanes in benzene afforded several kinds of product after column chromatography on silica gel; acyl allyl quinones, acyl allyl epoxy quinones, cyclopentanoid compounds including stannyl moiety, allyl hydroxy quinones, acyl hydroquinones, and acyl allyl hydroquinones. The main product comprises cyclopentanoid compounds, which are novel [2+ 3] cyclo adducts with 1, 2-migration of trialkylstannyl ...