Direct construction of silicon–silicon bond by using the low-valent titanium reagent

G Lai, Z Li, J Huang, J Jiang, H Qiu, Y Shen

文献索引：Lai, Guoqiao; Li, Zhifang; Huang, Jiabang; Jiang, Jianxiong; Qiu, Huayu; Shen, Yongjia Journal of Organometallic Chemistry, 2007 , vol. 692, # 16 p. 3559 - 3562

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摘要

The reductive dimerization or polymerization of organochlorosilanes has been achieved by using the low-valent titanium reducing agent other than the alkali metals that are invariable used in the Wurtz-type coupling reaction. Applying this method, the corresponding disilanes or poly (methylvinylsilane) was obtained in good yields. The poly (methylvinylsilane) synthesized by this method is highly pure with a high molecular weight and a narrow ...