Hydrosilylation of cyclohexene and allyl chloride with trichloro-, dichloro (methyl)-, and chlorodimethylsilanes in the presence of Pt (0) complexes

…, PA Storozhenko, SP Knyazev, GN Turkel'taub…

文献索引：Belyakova; Chernyshev; Storozhenko; Knyazev; Turkel'taub; Parshina; Kisin Russian Journal of General Chemistry, 2006 , vol. 76, # 6 p. 925 - 930

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被引用次数: 9

摘要

Abstract Hydrosilylation of cyclohexene and allyl chloride in the presence of Pt (0) complexes with tetramethyldivinyldisiloxane (Karstedt catalyst) and hexavinyldisiloxane was studied. It was shown that these catalysts are much more active in the hydrosilylation of cyclohexene with trichloro-, dichloro (methyl)-, and chlorodimethylsilane than the Pt (II)- containing Speier catalyst. In the hydrosilylation of allyl chloride in the presence of Pt (0) ...