Gas-phase heteroaromatic substitution. 12. Reaction of free trifluoromethyl cation with simple five-membered heteroarenes in the gas phase

R Bucci, G Laguzzi, ML Pompili…

文献索引：Journal of the American Chemical Society, , vol. 113, # 12 p. 4544 - 4550

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被引用次数: 19

摘要

... 0 1991 American Chemical Society ... The relevant thermo- chemistry is equal to IP,(heteroarene) + EA,(E'). For electrophiles E+ with the same geometry of ground-state E', IP ... Pyrrole (I), N-methylpyrrole (2). furan (3), and thiophene (4) were research grade chemicals from Fluka AG ...