Journal of Organometallic Chemistry

Synthesis of rhodium complexes derived from benzimidazolin-2-ylidene ligands and first used for the addition of arylboron to benzonitriles

S Demir, M Yiğit, İ Özdemir

文献索引：Demir, Serpil; Yigit, Murat; Oezdemir, Ismail Journal of Organometallic Chemistry, 2013 , vol. 732, p. 21 - 26

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被引用次数: 2

摘要

Benzimidazolium salts and their new rhodium complexes ([Rh (COD)(NHC) Cl]) were synthesized and characterized by elemental analysis, 1H NMR, 13C NMR, and IR spectroscopy. The addition of arylboron to benzonitriles in the presence of a catalytic amount of rhodium NHC complexes was examined. Corresponding carbonyl compounds were obtained in good yields. This method allows for the preparation of a wide variety of ...