Journal of organometallic chemistry

Hydroformylation of nitrogen-containing cyclic olefins via “in-situ” rhodium-phosphine catalysts

K Prókai-Tátrai, S Tőrös, B Heil

文献索引：Prokai-Tatrai, K.; Toeroes, S.; Heil, B. Journal of Organometallic Chemistry, 1986 , vol. 315, p. 231 - 236

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被引用次数: 11

摘要

Abstract Hydroformylation of nitrogen-containing cyclic olefins (N-substituted nortropidines, N-methyl-1, 2, 3, 6-tetrahydropyridine (THP) with rhodium-PR 3 catalysts prepared “in situ” is reported. The nortropidines reacted rapidly when either trialkyl-or triaryl-type phosphines were used, and the regioselectivities were not significantly influenced by the nature of the phosphine. With the less basic THP the rates and selectivities were generally lower, and ...