The Journal of Organic Chemistry

Photochemical Reactions of Halo-/Aryl Sulfide-Substituted Alkyl Phenylglyoxylate, an Assessment of the Lifetime of the Intermediate 1, 4-Biradical

S Hu, DC Neckers

文献索引：Hu, Shengkui; Neckers, Douglas C. Tetrahedron, 1997 , vol. 53, # 21 p. 7165 - 7180

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被引用次数: 13

摘要

Photochemical reactions of several halo/aryl sulfide-substituted alkyl phenylglyoxylates (1) were studied. For 2'-bromo-(1b), 2'-iodo-(1c), 2'-(phenylthio)-(1d), and 2'-(phenylsulfinyl)- (1e) ethyl phenylglyoxylate, vinyl phenylglyoxylate (2), proposed to be the result of β-