Abstract The preparation and spectral properties often novel methyl 5-[(o-, m-, and p- substituted)-phenylthio]-2-benzimidazolecarbamates with possible pharmacological activity as antihelmintics is described; by condensation and cyclization between 5-methylthioures sulfate chloroformic acid methyl ester and 3, 4-diaminophenyl-substituted-phenylthio ether dissolved in ethanol. The structures of all final products were corroborated by ir; 1 H-nmr, ...