Interaction of 1-tert-perfluorobutyl-3, 3-di (perfluoromethyl)-2-aziridinone with weak nucleophiles
DI Del'tsova, NP Gambaryan
文献索引：Del'tsova, D. I.; Gambaryan, N. P. Russian Chemical Bulletin, 1993 , vol. 42, # 2 p. 333 - 336 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1993 , # 2 p. 372 - 374
Abstract The title perfluoro-α-lactam (1) was found to react with N, N-dimethylformamide to give initially a betaine (2) which undergoes ring enlargement to produce the isomeric 2- dimethylamino-3, 4, 4-tri (perfluoroalkyl) substituted 5-oxazolidone (3). Related betaines were also obtained on reaction of 1 with pyridine, quinoline, benzalaniline, and p- dimethylaminobenzaldehyde.
