Photochemical synthesis and electronic spectra of fulminene ([6] phenacene)

H Okamoto, M Yamaji, S Gohda, K Sato…

文献索引：Okamoto, Hideki; Yamaji, Minoru; Gohda, Shin; Sato, Kaori; Sugino, Hisako; Satake, Kyosuke Research on Chemical Intermediates, 2013 , vol. 39, # 1 p. 147 - 159

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被引用次数: 11

摘要

Abstract Facile synthesis of fulminene ([6] phenacene) was achieved through the Mallory reaction of 1-(1-naphthyl)-2-(1-phenanthryl) ethene or the 9-fluorenone-sensitized photo- ring-closure of 1-(1-naphthyl)-2-(1-phenanthryl) ethane. The electronic spectral properties of fulminene were investigated for the first time using photoluminescence as well as transient absorption spectroscopy. The spectral features were compared with those of a series of ...