Organometallics

Bis (dimethylgermyl) alkane-iron tetracarbonyls: synthesis, photolysis, and reactivity

J Barrau, N Ben Hamida, A Agrebi, J Satge

文献索引：Barrau, Jacques; Hamida, Najib Ben; Agrebi, Abdelhamid; Satge, Jacques Organometallics, 1989 ,  vol. 8, p. 1585 - 1593            

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被引用次数: 13

摘要

This work concerns the synthesis, spectroscopic analysis, and reactivity of tetracarbonyliron bis (dimethylgermy1) alkanes MezGe (CHz), Ge (Mez) Fe (C0) 4 (n= 1, 2). These heterocycles are obtained by cyclization of bis (dimethylgermy1) alkanes MezHGe (CHz), GeHMez (n= 1, 2) with Fe (C0) 5 under UV irradiation. They are stable at room temperature, but the heterocycle with n= 1 decomposes under prolonged UV irradiation with formation ...