Preparation of substituted acetoxy silanes

HA Schuyten, JW Weaver, JD Reid

文献索引：Schuyten; Weaver; Reid Journal of the American Chemical Society, 1947 , vol. 69, p. 2111

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被引用次数: 32

摘要

Summary 1. Hydrogen-halogen exchange reactions of triethylsilane with three aliphatic chlorides in the presence of aluminum chloride are reported. 2. n-Hexyl chloride gave n- hexane; neopentyl chloride and neopentylcarbinyl chloride gave the rearrangement products, isopentane and 2, 3-dimethylbutane, respectively. A mechanism for exchange of silicon-hydrogen with carbon-chlorine in the presence of aluminum chloride is proposed. ...