Reduction of arylmethyl chlorides with a phosphine-hydrogen mixture in the KOH-DMSO system

SF Malysheva, VA Kuimov, BG Sukhov…

文献索引：Malysheva; Kuimov; Sukhov; Gusarova Russian Journal of General Chemistry, 2005 , vol. 75, # 4 p. 658 - 659

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摘要

We used the example of benzyl chloride (Ia) and 1-chloromethylnaphthalene (Ib) to show for the first time that arylalkyl chlorides can be reduced with phosphine generated together with hydrogen from red phosphorus in the KOH3water3organic solvent (dioxane, toluene) system [1]. The reaction is accomplished by bubbling the phosphine3hydrogen mixture through the arylmethyl chloride I3KOH3DMSO system heated to 85390oC. The yields of toluene IIa ...