The Journal of Physical Chemistry B

The nature of the sodium dodecylsulfate micellar pseudophase as studied by reaction kinetics

L Onel, NJ Buurma

文献索引：Onel, Lavinia; Buurma, Niklaas J. Journal of Physical Chemistry B, 2011 , vol. 115, # 45 p. 13199 - 13211

全文：HTML全文

被引用次数: 18

摘要

The nature of the rate-retarding effects of anionic micelles of sodium dodecyl sulfate (SDS) on the water-catalyzed hydrolysis of a series of substituted 1-benzoyl-1, 2, 4-triazoles (1a–f) has been studied. We show that medium effects in the micellar Stern region of SDS can be reproduced by simple aqueous model solutions containing small-molecule mimics for the surfactant headgroups and tails, namely sodium methyl sulfate (NMS) and 1-propanol, in ...