Tetrahedron

Bicyclopentanoid sesquiterpenes. the synthesis of cedranoid sesquiterpenes via the photo-rearrangement of bicyclo [2.2. 2] octenones

P Yates, KE Stevens

文献索引：Yates, Peter; Stevens, K. E. Tetrahedron, 1981 , vol. 37, # 25 p. 4401 - 4410

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被引用次数: 42

摘要

(±)-exo-2, 6, 6-Trimethyltricyclo [5.3. 1.01, 5] undecane-8, 10-dione (11) has been synthesized from dimethyl 6, 6-dimethyl-5-oxobicyclo [2.2. 2] oct-7-ene dicarboxylate (17). This constitutes a new synthesis of cedrol (3) since 11 has previously been converted to this compound.