Journal of Organometallic Chemistry

Reactions of aromatic sulphenyl compounds with organotin compounds

JL Wardell, S Ahmed

文献索引：Wardell,J.L.; Ahmed,S. Journal of Organometallic Chemistry, 1974 , vol. 78, p. 395 - 404

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被引用次数: 41

摘要

Aromatic sulphenyl halides and thiocyanates, RSX, cleave aryltin bonds, ArSn , when the aryl groups contain strongly electron releasing substituents, to give monosulphides, RSAr. The reaction of o-NO 2 C 6 H 4 SCl and Ph 3 SnCHCH 2 gave both the cleavage product, CH 2 CHSC 6 H 4 NO 2 -o, and the addition product, Ph 3 SnCHClCH 2 SC 6 H 4 NO 2 -o. Other organotin bonds cleaved by o-NO 2 C 6 H 4 SCl are p-MeC 6 H 4 SCH 2 CH 2 Sn (to ...