Catalytic asymmetric reduction of allylic esters with formic acid catalyzed by palladium-MOP complexes

…, M Naito, Y Matsumoto, Y Uozumi, M Miki…

文献索引：Hayashi, Tamio; Iwamura, Hiroshi; Naito, Masaki; Matsumoto, Yonetatsu; Uozumi, Yasuhiro; Miki, Misao; Yanagi, Kazunori Journal of the American Chemical Society, 1994 , vol. 116, # 2 p. 775 - 776

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被引用次数: 158

摘要

The palladium-catalyzed reduction of ailylicesters with formic acid developed by Tsuji and co-workers' provides a convenient method for regioselective synthesis of less-substituted olefins. Mechanistic studies2 on the catalytic reduction have revealed thatthe olefin is produced by reductive elimination from the key intermediate, Pd (II)(? r-allyl)(hydrido)(L), which is generated by the decarboxylation of the palladium formate complex, and that the ...