Heteroatom Chemistry

Reaction of diethyl thiocyanatomethylphosphonate with aldehydes as a route to diethyl Z??1??alkenylphosphonates

R Błaszczyk, T Gajda

文献索引：Blaszczyk, Roman; Gajda, Tadeusz Heteroatom Chemistry, 2007 , vol. 18, # 7 p. 732 - 739

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被引用次数: 25

摘要

Abstract Diastereoselective synthesis of diethyl Z-1-alkenylphosphonates from easily available diethyl thiocyanatomethylphosphonate and aromatic aldehydes has been developed. Olefination of the aldehydes occurs under mild conditions and affords the title compounds with moderate yields. A plausible mechanism of the above-mentioned reaction is also discussed.© 2007 Wiley Periodicals, Inc. Heteroatom Chem 18: 732–739, 2007; ...