Titanium and zirconium complexes containing a novel dianionic trifunctional amido ligand

…, IJ Scowen, AJ Edwards, M McPartlin

文献索引：Friedrich, Stefan; Schubart, Martin; Gade, Lutz H.; Scowen, Ian J.; Edwards, Andrew J.; McPartlin, Mary Chemische Berichte, 1997 , vol. 130, # 12 p. 1751 - 1759

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被引用次数: 68

摘要

Abstract The novel tridentate diamidoamine ligands [RC (2 C 5 H 4 N)(CH 2 NSiMe 3) 2) 2−(R= H, CH 3) have been synthesized and coordinated to Ti IV giving the pentacoordinate complexes [MX 2 (RC (2-C 5 H 4 N)(CH 2 NSiMe 3) 2}](M= Ti, Zr; X= Cl, Br). The crystal structure analysis of [TiBr 2 {HC (2-C 5 H 4 N)(CH 2) 2}](M= Ti, Zr; X= Cl, Br). The crystal structure analysis of [TiBr 2 {HC (2-C 5 H 4 N)(CH 2 NSiMe 3))](10b) confirmed the ...