Journal of Fluorine Chemistry

Formation of perfluorinated polyphenylenes by multiple pentafluorophenylation using C 6 F 5 Si (CH 3) 3

M Nishida, Y Hayakawa, T Ono

文献索引：Nishida, Masakazu; Hayakawa, Yoshio; Ono, Taizo Journal of Fluorine Chemistry, 2010 , vol. 131, # 12 p. 1314 - 1321

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被引用次数: 3

摘要

Pentafluorophenylation of perfluoroarenes with C6F5Si (CH3) 3 was investigated by using NMR and MALDI–TOF–MS techniques. Successive multiple pentafluorophenylation easily occurred not only on the para-position but also on the ortho-positions to provide perfluorinated p-phenylene and m-phenylene compounds. The perfluoroarenes having electron-withdrawing substituents provided oligo-to poly-(phenylene) s depending on the ...