An unusual dimerization of primary unsaturated alcohols catalyzed by RuHCl (CO)(PPh 3) 3

…, T Fukuyama, S Minamino, G Husson, I Ryu

文献索引：Doi, Takashi; Fukuyama, Takahide; Minamino, Satoshi; Husson, Guillaume; Ryu, Ilhyong Chemical Communications, 2006 , # 17 p. 1875 - 1877

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被引用次数: 2

摘要

The isomerization of carbon–carbon double bonds, a process catalyzed by metal hydride complexes via hydrometalation and subsequent β-hydride elimination, is among the most familiar reactions in transition metal chemistry. 1 Ruthenium hydride complexes are used in such alkene-isomerization reactions, 2–4 in which RuHCl(CO)(PPh 3 ) 3 is the most frequently used catalyst. 3 While the isomerization of secondary unsaturated alcohols to the corresponding saturated ketones ...