Aromatic thiocyanation using supported copper (I) thiocyanate
JH Clark, CW Jones, CVA Duke…
文献索引:Clark, James H.; Jones, Craig W.; Duke, Catherine V. A.; Miller, Jack M. Journal of the Chemical Society, Chemical Communications, 1989 , # 2 p. 81 - 82
Aromatic thiocyanates may be prepared by several different methods, the most common of which is conversion of the diazotised primary aromatic amines with metal thiocyanatesl although the activating effect of the diazonium group may lead to displacement of another substituent in the molecule.2 The major problem with thiocyanations is the production of the corresponding, thermodynamically more stable isothio- cyanate, often in appreciable quantities.' It has been reported that ...