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Journal of Heterocyclic Chemistry

4??Acyl??1, 2, 3??thiadiazoles from 4??aminoisothiazoles

FT Lee, GP Volpp

文献索引:Lee,F.T.; Volpp,G.P. Journal of Heterocyclic Chemistry, 1970 , vol. 7, p. 415 - 418

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被引用次数: 2

摘要

When preparing heterocyclic disulfides, we encountered an interesting rearrangement involving the 4-isothiazolediazonium salt and thiourea. Aromatic diazonium salts have long been known to react with aqueous thiourea to give the corresponding thiophenols (I). Recently, Kealy and Freiser (2) reported the preparation of 8-mercaptoquinoline from 8- aminoquinoline and thiourea. The method was described as rapid and simple with much ...