The Journal of Organic Chemistry

Reduction with metal ammonia combinations. III. Synthesis of. beta.-and. gamma.-alkylthiomercaptans from 1, 3-ditholanes and 1, 3-dithianes

BC Newman, EL Eliel

文献索引：Newman,B.C.; Eliel,E.L. Journal of Organic Chemistry, 1970 , vol. 35, # 11 p. 3641 - 3646

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被引用次数: 25

摘要

Recently, the calcium-ammonia reduction of 1, 3-oxathiolanes and l, 3-oxathianes has been reported'as a fairly general preparative method for p-and y-alkoxy mercaptans, respectively. It is evident that selective cleavage of the CS bond of 1, 3-dithiolanes and 1, 3-dithianes (Scheme I) would provide a convenient route