New metal-assisted synthesis of tetrakis (trifluoromethyl) tetrathiafulvalene

C Bianchini, A Meli

文献索引：Bianchini, Claudio; Meli, Andrea Journal of the Chemical Society, Chemical Communications, 1983 , # 22 p. 1309 - 1310

全文：HTML全文

被引用次数: 0

摘要

Replacement of the 1, 3-dithiolium carbene ligand by CO or F3CCCCF3 in the complex [(triphos) Ni {CS2C2 (CF3) 2}][triphos= 1, 1, 1-tris (diphenylphosphinomethyl) ethane] affords the complexes [(triphos) Ni (CO)] or [(triphos) Ni (F3CCCCF3)], whereas the 1, 3-dithiolium carbene dimerizes to tetrakis (trifluoromethyl) tetrathiafulvalene.